Back to Top
Skip to main content
NETL Logo
Blended Rubbery Polymer for Gas Separation
NETL Ref No.  
23N-05
Patent Status

A provisional patent application has been filed.

Main Visual
Gas separation properties of NETL’s blended rubbery polymer membrane (green dot).
Main Visual Caption

Gas separation properties of NETL’s blended
rubbery polymer membrane (green dot).

Introduction

Opportunity

The U.S. Department of Energy’s National Energy Technology Laboratory (NETL) has developed a method for creating advanced polymer membranes to efficiently separate carbon dioxide (CO2) from nitrogen (N2). These membranes combine excellent CO2 permeability, selectivity and stability, even in humid conditions, making them ideal for industrial applications like CO2 capture from flue gas. NETL’s rubbery blend membrane resists aging and humidity and exceeds Robeson’s 2008 upper bound for CO2/N2 separation. By exhibiting high CO2 permeance (up to 4,500 GPU), moderate CO2/N2 selectivity (40) and long-term stability, it can efficiently separate CO2 from flue gas in power plants and industrial facilities, providing a more stable and cost-effective alternative to traditional amine-based capture systems. High molecular weight facilitates thin-film coating, enabling defect-free membranes as thin as 120 nm. It is a versatile platform for CO2 separation, medical devices and other applications requiring robust, high-performance membranes. This invention is available for licensing and/or further collaborative research from NETL.

Overview

Problems Addressed

  • Industrial processes that require CO2/N2 separation often depend on membranes that can provide high permeability and selectivity. However, these materials have poor mechanical integrity and aging resistance.
  • Other solutions lack robustness and performance when exposed to humidity or prolonged use.
  • Complex fabrication steps and difficulties in achieving thin, defect-free films that do not degrade in the presence of water vapor or fluctuating temperatures further complicate efforts, underscoring the need for more reliable, high-performance membrane materials.

Inventors

David Hopkinson, Lingxiang Zhu and Victor Kusuma

Download Tech Brief

Benefits

Advantages

Features higher CO2 permeability compared to cellulose acetate.
Balances permeability and selectivity at levels surpassing established performance limits.
Maintains adaptability for diverse industrial application.

Applications

Uses
  • Industrial CO2 separation: efficiently removing CO2 from flue gas and other industrial gas streams.
  • CO2 conversion membrane reactors: for processes designed to convert or utilize CO2.
  • Biomedical and hydrogel-based applications: wound dressings, tissue engineering and drug delivery.
Date Posted: 
Date Posted
November 25, 2025

 

Learn more about NETL's Available Technologies.