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Chevrel-Phase Cathodes for Rechargeable Magnesium Batteries
NETL Ref No.  
13N-14
Patent Status

A U.S. patent (US9947962) was issued on April 17, 2018, and expires on May 18, 2036.

Main Visual
SEM images of Cu2Mo6S8 and acid leached Mo6S8 obtained by precursor route
Main Visual Caption

SEM images of Cu2Mo6S8 and acid leached Mo6S8 obtained by precursor route.

Introduction

Opportunity

Advancing rechargeable magnesium batteries depends on cathode materials that can accommodate multivalent Mg2+ insertion without structural collapse while also being produced through practical, scalable synthesis routes. Conventional preparation of Chevrel-phase Mo6Z8 compounds often requires sealed ampoules, extended heat treatments and handling of reactive precursors, creating safety concerns and limiting throughput. To address these constraints, researchers at the U.S. Department of Energy’s National Energy Technology Laboratory (NETL) and the University of Pittsburgh (Pitt.), developed a precursor-driven synthesis that forms Chevrel-phase structures through controlled thermal conversion of mixed metal compounds rather than sealed-vessel reactions. This route enables more uniform stoichiometry, reduces processing time and improves phase purity. The resulting materials exhibit stable and reversible magnesium intercalation and can be integrated with compatible electrolytes to assemble robust cells for high-capacity energy storage. This technology is available for licensing and/or further collaborative research from NETL in partnership with Pitt.

Overview

Problems Addressed

  • Conventional Chevrel-phase synthesis requires long high-temperature processing in sealed ampoules, leading to high cost, sulfur vapor hazards and non-stoichiometric products.
  • Many precursor routes require hydrogen atmospheres or extended chemical leaching, limiting scalability.
  • Magnesium battery development is hindered by electrolytes that block Mg2+ transport.
  • Existing cathode materials may not support reversible intercalation of divalent ions such as Mg2+.

Publications

P. Kumta, et al. Cathodes and electrolytes for rechargeable magnesium batteries and methods of manufacture. (2018). United States Patent and Trademark Office. U.S. Patent No. 9,947,962.

Inventors

Prashant Kumta, Partha Saha, Moni Kanchan Datta and Ayyakkannu Manivannan

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Benefits

Advantages
  • Precursor-based synthesis enables direct, scalable formation of MxMo6Z8 and Mo6Z8 Chevrel-phase materials.
  • Chevrel-phase structures support reversible Mg2+ intercalation at room temperature.
  • High-energy mechanical milling and precursor mixing reduce synthesis time relative to prolonged solid-state or ampoule-based methods.

Applications

Uses
  • Rechargeable magnesium batteries using Chevrel-phase cathodes.
  • Electrochemical cells incorporating cathodes derived from precursor-based synthesis routes.
  • Energy storage systems requiring solid cathodes with reversible metal-ion intercalation.
Date Posted: 
Date Posted
January 22, 2026

 

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