Proceedings - 2017 NETL CO2 CAPTURE TECHNOLOGY PROJECT REVIEW MEETING

2017 NETL CO₂ CAPTURE TECHNOLOGY PROJECT REVIEW MEETING

August 21-25, 2017

Meeting Summary

Proceedings of the 2017 NETL CO₂ Capture Technology Project Review Meeting

Table of Contents

Presentations

• Monday, August 21, 2017
  • Opening Session
  • NETL Research & Innovation Center - Carbon Capture
  • Systems Studies and Modeling
  • CO₂ Compression
  • Carbon Capture Pilot-Scale Research
• Tuesday, August 22, 2017
  • Carbon Capture Pilot-Scale Research
  • Carbon Capture Lab/Bench-Scale Research
• Wednesday, August 23, 2017
  • Carbon Capture Simulation for Industry Impact (CCSI²)
  • NETL Research & Innovation Center – Carbon Use and Reuse
  • Carbon Use and Reuse
• Thursday, August 24, 2017
  • Discovery of Carbon Capture Substances and Systems
  • Carbon Capture Lab/Bench-Scale Research
• Friday, August 25, 2017
  • NETL Research & Innovation Center – Oxy-Combustion and Chemical Looping
  • Oxy-Combustion and Chemical Looping

Poster Presentations

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PRESENTATIONS

Monday, August 21, 2017
OPENING SESSION

• Welcoming Remarks
  Lynn Brickett, U.S. Department of Energy, National Energy Technology Laboratory
• Future of Fossil Fuels-Impacts of Innovation and Demand
  John Litynski, U.S. Department of Energy, Office of Fossil Energy
• CO₂ Capture R&D at EPRI
  Abhoyjit Bhown, Electric Power Research Institute
• Learning from Doing: CCUS Reference Cases
  Keith Burnard, IEA Greenhouse Gas
• TCM’s First 5 Years of Operation and Norway Advancing to Full Scale CCS on Industrial Flue Gas Sources
  Bjorn-Erik Haugan, Gassnova SF
• TCM Mitigation Solutions to High Amine Emissions Due to Aerosols and Particulates Contained in Oil Refinery Flue Gases
  Thomas De Cazenove, CO₂ Technology Centre Mongstad (TCM)
• Retrofitting CCS to Coal-Fired Power Plants in Australia
  Geoff Bongers, Gamma Energy Technology
• International Test Center Network Update
  Frank Morton, Southern Company Services, Inc.

NETL RESEARCH & INNOVATION CENTER - CARBON CAPTURE

• Experimental Materials Development in Mixed Matrix Membranes for Post-Combustion Carbon Capture
  Surendar Venna, U.S. Department of Energy, National Energy Technology Laboratory
• Design of Novel Mixed Matrix Membrane Using High Throughout Computational Methods
  Jan Steckel, U.S. Department of Energy, National Energy Technology Laboratory
• Experimental Materials Development and Bench-Scale System Design for Pre-Combustion Solvents
  Nicholas Siefert, U.S. Department of Energy, National Energy Technology Laboratory
• Screening of Materials for Pre-Combustion Solvents Using a Combined Approach of Data Mining and Molecular Simulation
  Wei Shi, U.S. Department of Energy, National Energy Technology Laboratory

SYSTEMS STUDIES AND MODELING

• Post-Combuston Capture Retrofit/Eliminating the De-Rate Study
  Jeff Hoffmann, U.S. Department of Energy, National Energy Technology Laboratory
• Systems Analysis: Process Assumptions and Data Gaps
  Mark Woods, U.S. Department of Energy, National Energy Technology
  Laboratory
• SEA Post-Combustion Analysis Update
  Timothy Fout, U.S. Department of Energy, National Energy Technology Laboratory

CO₂ COMPRESSION

• Advanced CO₂ Compression with Supersonic Technology (FE0026727)
  Ravi Srinivasan, Dresser-Rand Company

CARBON CAPTURE PILOT-SCALE RESEARCH

• Advanced Technology Testing at the National Carbon Capture Center (FE0022596)
  John Carroll, Southern Company Services, Inc.
• Pilot Test of a Nanoporous, Super-Hydrophobic Membrane Contactor Process for Post-Combustion Carbon Dioxide Capture (FE0012829)
  Shiguang Li, Gas Technology Institute
• ION Advanced Solvent CO₂ Capture Pilot Project (FE0013303)
  Erik Meuleman, ION Engineering, LLC
• Application of a Heat Integrated Post-Combustion Carbon Dioxide Capture System with Hitachi Advanced Solvent into Existing Coal-Fired Power Plant (FE0007395)/An Advanced Catalytic Solvent for Lower Cost Post-Combustion CO₂ Capture in a Coal-Fired Power Plant (FE0012926)
  Kunlei Liu, University of Kentucky Center for Applied Energy Research

Tuesday, August 22, 2017
CARBON CAPTURE PILOT-SCALE RESEARCH

• Integrated Testing of a Membrane Carbon Dioxide Capture Process with a Coal-Fired Boiler (FE0026414)
  Tim Merkel, Membrane Technology & Research, Inc.
• Pilot Test of Novel Electrochemical Membrane System for Carbon Dioxide Capture and Power Generation (FE0026580)
  Hossein Ghezel-Ayagh, FuelCell Energy, Inc.
• Pilot Scale Evaluation of Pre-Combustion Carbon Capture Process (FE0013105)
  Gokhan Alptekin, TDA Research, Inc.
• Sorbent Based Post-Combustion CO₂ Slipstream Testing (FE0012870)
  Jeannine Elliott, TDA Research, Inc.
• Waste Heat Integration with Solvent Process for More Efficient CO₂ Removal from Coal-Fired Flue Gas (FE0007525)
  Shintaro Honjo, Mitsubishi Heavy Industries America, Inc.
• Dilute Source Carbon Dioxide Capture: Management of Atmospheric Coal-Produced Legacy Emissions (FE0026861)
  Dan Kahn, Carbon Engineering

CARBON CAPTURE LAB/BENCH-SCALE RESEARCH

• Zeolite Membrane Reactor for Pre-Combustion Carbon Dioxide Capture (FE0026435)
  Jerry Lin, Arizona State University
• Sorption Enhanced Mixed Matrix Membranes for H₂ Purification and CO₂ Capture (FE0026463)
  Haiqing Lin, University of Buffalo, The State University of New York
• Development of a Novel Biphasic CO₂ Absorption Process with Multiple Stages of Liquid-Liquid Phase Separation for Post-Combustion Carbon Capture (FE0026434)
  Yongqi Lu, Illinois State Geological Survey, University of Illinois at Urbana - Champaign
• Large Bench Scale Development of Non-Aqueous Solvent Carbon Dioxide Capture Process for Coal Fired Power Plants Utilizing Real Coal Derived Flue Gas (FE0026466)
  S. James Zhou, RTI International
• A High Efficiency, Ultra-Compact Process for Pre-Combustion CO₂ Capture (FE0026423)
  Vasilios Manousiouthakis, University of Southern California
• Lab-Scale Development of a Hybrid Capture System with Advanced Membrane, Solvent System, and Process Integration (FE0026464)
  David Luebke, Liquid Ion Solutions
• Energy Efficient Go-Peek Hybrid Membrane Process for Post-Combustion Carbon Dioxide Capture (FE0026383)
  Shiguang Li, Gas Technology Institute
• Evaluation of Amine-Incorporated Porous Polymer Networks (aPPNS) as Sorbents for Post-Combustion CO₂ Capture (FE0026472)
  Hong Cai Zhou, Texas A&M University
• Novel CO₂-Selective Membranes for CO₂ Capture from less than 1% CO₂ Sources (FE0026919)
  Winston Ho, Ohio State University
• Bench Scale Testing of Next Generation Hollow Fiber Membrane Modules (FE0026422)/ CO₂ Capture by Cold Membrane Operation with Actual Power Plant Flue Gas (FE0013163)
  Alex Augustine, American Air Liquide, Inc.

Wednesday, August 23, 2017
CARBON CAPTURE SIMULATION FOR INDUSTRY IMPACT (CCSI²)

• CCSI² Program Overview & CCSI Toolset Introduction
  Michael Matuszewski, CCSI²
• CCSI Partnership Evolution: CCSI² Industrial and Academic Stakeholders Board
  John Shinn, CCSI²
• Multi-Scale Modeling: Micro-Encapsulated Carbon Sorbent (MECS) Technology
  Debangsu Bhattacharyya, West Virginia University
  Benjamin Omell, U.S. Department of Energy, National Energy Technology Laboratory
  Janine Carney, U.S. Department of Energy, National Energy Technology Laboratory
  Zhijie Xu, Pacific Northwest National Laboratory
• Modeling Amine Aerosol Formation with Piperazine Solvent
  Yue Zhang, University of Texas at Austin
• Modeling Packing Performance Parameters
  Di Song, University of Texas at Austin
• Solvent Pilot System Test Campaign Guidance: Collaboration with National Carbon Capture Center & Test Centre Mongstad
  Debangsu Bhattacharyya, West Virginia University
  Brenda Ng, Lawrence Livermore National Laboratory
  James Gattiker, Los Alamos National Laboratory
• CCSI Toolset Support: Open Source Release Management
  Keith Beattie, Lawrence Berkeley National Laboratory

NETL RESEARCH & INNOVATION CENTER – CARBON USE AND REUSE

• Combining Experiment and Computation to Design CO₂ Conversion Nanocatalysts
  Douglas Kauffman, U.S. Department of Energy, National Energy Technology Laboratory

CARBON USE AND REUSE

• A Microalgae-Based Platform for the Beneficial Reuse of Carbon Dioxide Emissions from Power Plants (FE0026396)
  Mark Crocker, University of Kentucky
• Microalgae Commodities from Coal-Fired Power Plant Flue Gas CO₂ (FE0026490)
  John Benemann, MicroBio Engineering, Inc.
• CO₂ to Bioplastics: Beneficial Re-use of Carbon Emissions from Coal-Fired Power Plants Using Microalgae (FE0029623)
  Mark Crocker, University of Kentucky Research Foundation
• Upcycled 'CO₂-Negative' Concrete for Construction Functions (FE0029868)
  Gaurav Sant, University of California, Los Angeles
• Electrochemical Conversion of Carbon Dioxide to Alcohols (FE0029868)
  Feng Jiao, University of Delaware
• Nano-Engineered Catalyst Supported on Ceramic Hollow Fibers for the Utilization of CO₂ in Dry Reforming to Produce Syngas (FE0029760)
  Shiguang Li, Gas Technology Institute
• High Energy Systems for Transforming CO₂ to Valuable Products (FE0029787)
  Osman Akpolat, Gas Technology Institute
• Low Temperature Process Utilizing Nano-Engineered Catalyst for Olefin Production from Coal Derived Flue Gas (FE0029570)
  Jadid Samad, Southern Research Institute
• A New Process for CO₂ Conversion to Fuel (FE0029866)
  Gokhan Alptekin, TDA Research, Inc.

Thursday, August 24, 2017
DISCOVERY OF CARBON CAPTURE SUBSTANCES AND SYSTEMS

• Low-Viscosity, Water-Lean CO₂ BOLs with Polarity-Swing Assisted Regeneration (FWP-70924)
  David Heldebrant, Pacific Northwest National Laboratory
• High-Efficiency, Integrated Reactors for Sorbents, Solvents, and Membranes Using Additive Manufacturing (FWP-FEW0225)
  Joshuah Stolaroff, Lawrence Livermore National Laboratory
• Amine-Appended Metal-Organic Frameworks as Switch-Like Adsorbents for Energy-Efficient Carbon Capture (FWP-FP00006194)
  Jeffrey Long, Lawrence Berkeley National Laboratory
• Cryogenic Carbon Capture Development (FE0028697)
  Larry Baxter, Sustainable Energy Solutions
• Microencapsulation and Advanced Manufacturing to Enable New Solvents for Carbon Capture (FWP-FEW0194)
  Joshuah Stolaroff, Lawrence Livermore National Laboratory
• Hybrid Encapsulated Ionic Liquids for Post-Combustion Carbon Dioxide Capture (FE0026465)
  Mark McCready, University of Notre Dame
• Novel Process that Achieves 10 MOL/KG Sorbent Swing Capacity in a Rapidly Cycled Pressure Swing Adsorption Process (FE0026433)
  Ryan Lively, Georgia Tech Research Corporation
• Lab-Scale Development of a Solid Sorbent for CO₂ Capture Process for Coal-Fired Power Plants (FE0026432)
  Mustapha Soukri, Research Triangle Institute

CARBON CAPTURE LAB/BENCH-SCALE RESEARCH

• Bench-Scale Development of a Hybrid Membrane-Absorption CO₂ Capture Process (FE0013118)
  Brice Freeman, Membrane Technology & Research, Inc.
• Development of Mixed-Salt Technology for Carbon Dioxide Capture from Coal Power Plants (FE0012959)
  Indira Jayaweera, SRI International
• Development of a Pre-Combustion CO₂ Capture Process Using High-Temperature PBI Hollow Fiber Membranes (FE0012965)
  Indira S. Jayaweera, SRI International
• Evaluation of Piperazine with Advanced Flash Regeneration for CO₂ Capture from Coal-Fired Flue Gas (FE0005654)
  Gary Rochelle, University of Texas at Austin
• Accelerating the Development of "Transformational" Solvents for CO₂ Separations (FWP-65872)
  David Heldebrant, Pacific Northwest National Laboratory
• Robust and Energy Efficient Dual-Stage Membrane-Based Process for Enhanced Carbon Dioxide Recovery (FE0013064)
  Richard Ciora, Media and Process Technology, Inc.
• Combined Sorbent/WGS-Based CO₂ Capture Process with Integrated Heat Management for IGCC Systems (FE0026388)
  Andrew Lucero, Southern Research Institute
• Electrochemically-Mediated Sorbent Regeneration in CO₂ Scrubbing Processes (FE0026489)
  T. Alan Hatton, Massachusetts Institute of Technology

Friday, August 25, 2017
ADVANCED COMBUSTION SYSTEMS PRESENTATIONS AND POSTERS

NETL RESEARCH & INNOVATION CENTER – OXY-COMBUSTION AND CHEMICAL LOOPING

• Overview of Chemical Looping Efforts at the National Energy Technology Laboratory
  Doug Straub, U.S. Department of Energy, National Energy Technology Laboratory
• An Analysis of In Situ Phase Changes Occurring in Natural Hematite Exposed to Simulated High Temperature Redox Gas Cycling Encountered in Chemical Looping
  James Bennett, U.S. Department of Energy, National Energy Technology Laboratory

OXY-COMBUSTION AND CHEMICAL LOOPING

• Commercialization of the Iron Based Coal Direct Chemical Looping Process for Power Production with in situ Carbon Dioxide Capture (FE0009761)
  Luis Velazquez-Vargas, The Babcock & Wilcox Company
• 10 Megawatts Electric Coal Direct Chemical Looping Large Pilot Plant - Pre-Front End Engineering and Design Study (FE0027654)
  Andrew Tong, The Ohio State University
• Integrated Oxygen Production and CO₂ Separation Through Chemical Looping Combustion with Oxygen Uncoupling (FE0025076)
  Kevin Whitty, University of Utah
• Advanced Oxy-Combustion Technology Development and Scale Up for New and Existing Coal-Fired Power Plants (FE0009702)
  Richard Axelbaum, Washington University, St. Louis
• Integrated Flue Gas Purification and Latent Heat Recovery for Pressurized Oxy-Combustion (FE0025193)
  Richard Axelbaum, Washington University, St. Louis
• Enabling Technologies for Oxy-Fired Pressurized Fluidized Bed Combustor Development (FE0025160)
  Mark Fitzsimmons, Gas Technology Institute
• Oxy-Combustion Pressurized Fluidized Bed with Carbon Dioxide Purification (FE0009448)
  Mark Fitzsimmons, Gas Technology Institute
• Flue Gas Water Vapor Latent Heat Recovery for Pressurized Oxy-Combustion (FE0025350)
  Dexin Wang, Gas Technology Institute
• Characterizing Impacts of High Temperatures and Pressures in Oxy-Coal Combustion Systems (FE0025168)
  Andrew Chiodo, Reaction Engineering International
• Pre-Project Planning for a Flameless Pressurized Oxy-Combustion Pilot Plant (FE0027771)
  Joshua Schmitt, Southwest Research Institute
• High Efficiency Thermal Integration of Supercritical CO₂ Brayton Power Cycles for Oxy-Fired Heaters (FE0025959)
  Jeffrey Phillips, Electric Power Research Institute

Poster Presentations

POSTER PRESENTATIONS - CARBON CAPTURE AND CARBON USE AND REUSE

• Rapid Design and Testing of Novel Gas-Liquid Contacting Devices for Post-Combustion CO₂ Capture via 3-D Printing (SC0012056)
  Erik Meuleman, ION Engineering, LLC
• Membrane-Integrated Sorbent Adsorption Process for Carbon Capture (SC0011885)
  Gokhan Alptekin, TDA Research
• Algae-Based CO₂ Capture from Power Plants and Conversion to Value Added Products (SC0015719)
  Fred Harrington and Ravi Prasad, Helios-NRG, LLC
• Minimizing Solvent Oxidation with NO₂ Pre-Scrubbing (SC0015890)
  Andrew Sexton, Trimeric Corporation
• Electrochemical Conversion of CO₂ to Fuels for Power-to-Gas Energy Storage (SC0015879)
  Trent Molter, Sustainable Innovations, LLC
• Mitigation of Aerosol Emissions from Solvent-Based Post-Combustion CO₂ Capture Systems (SC0015737)
  Srivats Srinivasachar, Envergex, LLC
• Conversion of CO₂ to Alkyl Carbonates Using Ethylene Oxide as Feedstock (SC0013233)
  C.B. Panchal and Richard Doctor, E3Tec Service, LLC
• Electrochemical Reduction of Carbon Dioxide to Useful Chemical Intermediates
  Philip Cox, Mainstream Engineering
• Passive CO₂ Separation Membrane for Hot Flue Gases (SC0017124)
  Matthew Merrill, Luna Innovations, Inc.
• Computational Designing and Screening of Solid Materials for CO₂ Capture
  Wei Shi, U.S. Department of Energy, National Energy Technology Laboratory
• An Integrated Experimental and Modeling Approach to Mixed Matrix Membranes
  David Hopkinson, U.S. Department of Energy, National Energy Technology
  Laboratory
• Continuous Flow Processing of Inorganic Membranes on Polymeric Hollow Fiber Supports
  Surendar Venna, U.S. Department of Energy, National Energy Technology
  Laboratory
• High Throughput Computational Screening of Metal Organic Framework Based Mixed Matrix Membranes
  Samir Budhathoki, AECOM
• Predicting Foaming Behavior in Solvents Based on Physical Properties
  Surya Prakash Tiwari, U.S. Department of Energy, National Energy Technology
  Laboratory
• Ionic Liquid/Polyether Compatibility in Cross-Linked Ion Gel Membranes
  Megan Macala, AECOM
• CO₂ Rejecting Membranes (CRM) for Concentrating Dilute CO₂ Flue Gas Streams
  Indira Jayaweera, SRI International
• Effects of Plant Location on Costs of CO₂ Capture
  Keith Burnard and Monica Garcia, IEA Greenhouse Gas R&D Programme
• Multi-Component Liquid Analyzer for Solvent-Based CO₂ Capture Systems, Near Real-Time Feedback During Campaign in Industrial Environment
  Erik Meuleman, ION Engineering, LLC
• Polyamine-Based Facilitated Transport Membranes for Post-Combustion CO₂ Capture
  James S. Baker, U.S. Department of Energy, National Energy Technology
  Laboratory
• Enabling a Solid-State Carbon Dioxide Network
  Kevin S. Blinn, RRTC, Inc.
• In-Situ Evaluation of CaSiO₃ Carbonation
  Daniel Kopp, Rutgers, The State University of New Jersey
• Reduction Behavior and Kinetics of CuO Oxygen Carriers with Coal Char in a Fluidized Bed Drop Tube Reactor
  Ward Burgess, AECOM

POSTER PRESENTATIONS - OXY-COMBUSTION AND CHEMICAL LOOPING

• Method for Separation of Coal Conversion Products from Sorbents/Oxygen Carriers (SC0013832)
  Srivats Srinivasachar, Envergex, LLC
• Methodology for Attrition Evaluation of Oxygen Carriers in Chemical Looping Systems (SC0011984)
  Srivats Srinivasachar, Envergex, LLC
• Application of Spouting Fluidized Bed to Coal-Fueled Pressurized Chemical Looping Combustion (FE0025098)
  Kunlei Liu, University of Kentucky, Center for Applied Energy Research
• sCO₂ Cycles for Indirect Fossil Applications (FE0025348)
  Aaron McClung, Southwest Research Institute
• Characterizing Impacts of Dry Coal Feeding in High Pressure Oxy-Coal Combustion Systems (FE0029162)
  Kevin Davis, Reaction Engineering International
• Development of Enabling Technologies for a Pressurized Dry Feed Oxy-Coal Reactor (FE0029157)
  Bradley Adams, Brigham Young University
• Development of Enabling Technologies for Chemical Looping Combustion and Chemical Looping with Oxygen Uncoupling (FE0029160)
  Kevin Whitty, University of Utah
• Enabling Staged Pressurized Oxy-Combustion: Improving Flexibility and Performance at Reduced Cost (FE0029087)
  Jeffrey Phillips, Electric Power Research Institute
• Oxy-Combustion System Process Optimization (FE0029090)
  Gokhan Alptekin, TDA Research, Inc.
• Technology Demonstration of a High-Pressure Swirl Oxy-Coal Combustor (FE0029113)
  Arifur Choudhuri, University of Texas at El Paso
• Catalytic Removal of Oxygen and Pollutants in Exhaust Gases from Pressurized Oxy-Combustors (FE0029161)
  Yongqi Lu, Illinois State Geological Survey, University of Illinois at Urbana- Champaign