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Available Technologies

Title Date Posted Patent Information Sort descending Opportunity
Producing Carbon and Hydrogen With NETL’s Novel Iron-based Catalyst USPN 11,427,467

This new Iron-based catalyst will enable a one-step process to produce hydrogen - a promising energy source that is also environmentally benign - by directly converting methane. The catalyst will eliminate the need to first create syngas and then remove carbon dioxide. In addition to creating hydrogen, carbon, which is also a useful commodity is created as a by-product. This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge
The traditional commercial methods of forming hydrogen from methane are based on steam methane reforming, coal or bio-mass gasification, electrolysis, and thermo-chemical processes. Some of these methods are cost-effective, but each requires that syngas first be created and the water gas shift reaction be used to convert syngas to hydrogen and carbon dioxide. From there, the hydrogen must be purified using pressure swing adsorption to separate the hydrogen for the carbon dioxide. Developing a method that avoids these intermediate steps would reduce the cost of producing valuable hydrogen.

Encapsulation Method for More Durable Reactive Materials USPN 11,433,385

This invention describes a method of encapsulating reactive materials (i.e., catalyst, sorbent or oxygen carrier) within a porous, unreactive, strong outer layer to increase attrition resistance while retaining sufficient reactivity. This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge

Processes that involve fluidized bed or transport reactors require pellets with high attrition resistance because the pellets move continuously in the reactor during operation. Loss of pellets due to attrition contributes to high replacement costs and operational difficulties. Most processes that involve catalyst, sorbents and oxygen carriers operate in fluidized beds or circulating fluidized beds and require high attrition resistance for long-term operations. In addition, loss of reactive materials with low melting points, such as CuO, due to agglomeration is an issue. Pellets with high attrition resistance are needed to combat against loss of reactive materials.

Downhole Laser System With an Improved Laser Output Production and Data Collection USPN 11,451,004; U.S. Patent Pending

This patent-pending technology establishes a novel system and method for laser induced breakdown spectroscopy (LIBS) applications. The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge

Low-cost, efficient monitoring of remote locations has and continues to be highly sought in the industry. For example, drilling production or injection wells for oil/gas extraction or carbon dioxide (CO2) storage always has the potential for leakage into the surrounding formations and environment. The ability to measure the subsurface fluids in and around the injection/production area before and after subsurface activities becomes more important when there is a suspected leak. Current downhole monitoring systems rely on bulk parameters such as pH and conductivity. Lab based systems can provide trace element measurements of subsurface fluids but require fluids to be taken from the field and digested prior to measurement. A system that can provide trace element measurements in real time while deployed in the subsurface is potentially of great value.

Current diode pumped solid state (DPSS) laser systems used for laser induced breakdown spectroscopy applications in fluid system measurements have numerous limitations. First, the systems are susceptible to dimensional changes caused by temperature and pressure swings in fluctuating environments in downhole applications. A second issue is the size of the laser spark that is produced in the fluid for measurements affecting signal strength. The third issue is the efficient collection and transmission of the plasma emission for analysis.

Creep Resistant Ni-Based Superalloy Casting and Manufacturing USPN 11,453,051

This invention describes an improved casting and manufacturing method for a creep-resistant nickel-based superalloy for advanced high-temperature applications. This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge
In the future, advanced ultra-supercritical (A-USC) and/or supercritical carbon dioxide (sCO2) power plants are expected to raise efficiencies of coal-fired power plants from around 35 to greater than 50%. However, these advanced systems feature components that operate at high pressures and temperatures exceeding 760 degrees Celsius. These conditions cause gradual permanent deformation, known as creep, in components manufactured with currently used alloys like ferritic-martensitic high-strength steels and austenitic stainless steels.
Certain nickel-based super alloys such as Inconel 740H (IN740H) currently meet requirements for use in A-USC in a wrought version, but using the alloy in a cast form would be valuable in terms of the range of component size, geometries and complexities, and cost.
Previous efforts at casting IN740H have resulted in poor creep performance when compared to wrought versions. Furthermore, several compositions within the nominal specified range for IN740H have been investigated but failed to provide a material in the as-cast form that would withstand long-term, high temperature exposure in creep.
 

High-Performance Corrosion-Resistant High-Entropy Alloys USPN 11,466,344

The U.S. Department of Energy’s National Energy Technology Laboratory (NETL) developed designs, manufacturing processes, and corrosion property validations of new high-performance corrosion-resistant high-entropy alloys that are superior to and less expensive than existing alloys and demonstrate improved resistance to corrosion, including pitting corrosion in harsh environments and sea water.

Challenge
Metals and alloys used in sea water or acidic aqueous environments are prone to various forms of corrosion, including pitting and/or crevice corrosion because of the presence of aggressive salt, such sodium chloride (NaCl). Pitting and crevice corrosion can serve as initiation sites for developing cracks that will lead to catastrophic failures of the metallic components. The current solution to this problem is to coat the metals with nickel (Ni)-based superalloys such as Hastelloy® C276. Hastelloy®, which is very expensive.

Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures USPN 6,908,497

The Department of Energy’s National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 6,908,497, titled "Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures."

Disclosed in this patent is a new low-cost carbon dioxide (CO2) sorbent that can be used in large-scale gas-solid processes. Researchers have developed a new method to prepare these sorbents by treating substrates with an amine and/or an ether in a way that either one comprises at least 50 weight percent of the sorbent. The sorbent captures compounds contained in gaseous fluids through chemisorptions and/or physisorption between layers of the substrate lattice. The polar amine liquids are located within these layers. This method eliminates the need for high surface area supports and provides absorption capabilities independent of the sorbent surface area, and can be regenerated.

High Capacity Immobilized Amine Sorbents USPN 7,288,136

The Department of Energy’s National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,288,136 titled "High Capacity Immobilized Amine Sorbents."

Disclosed in this patent is the invention of a method that facilitates the production of low-cost carbon dioxide (CO2) sorbents for use in large-scale gas-solid processes. This method treats an amine to increase the number of secondary amine groups and impregnates the amine in a porous solid support. As a result of this improvement, the method increases CO2 capture capacity and decreases the cost of using an amine-enriched solid sorbent in CO2 capture systems.

A Unique Split Laser System for Environmental Monitoring USPN 7,421,166; USPN 8,786,840; USPN 8,934,511; USPN 9,297,696; USPN 9,548,585

Researchers at the U.S. Department of Energy’s National Energy Technology Laboratory (NETL) have developed a novel split laser system for in situ environmental monitoring via Laser Induced Breakdown Spectroscopy (LIBS) or Raman analysis.  The design features fiber-coupled, optically-pumped, passively Q-switched lasers that are small, portable, low cost and robust enough for even downhole applications.  The technology can be used in a wide array of applications, including, but not limited to, carbon dioxide (CO2) monitoring for CO2 sequestration, oil and gas monitoring, and water analysis (groundwater and municipal systems).  The technology is available for licensing and/or further collaborative research with NETL.

Proof of concept experimentation has been completed. NETL researchers are continuing to design miniaturized lasers and optical delivery systems to allow further size and cost reductions. The researchers have identified the need to complete and demonstrate both single point and multipoint measurement prototypes.  The results would further validate the technology and expedite its deployment to the private sector. 

Method for Determining Solids Circulation Rate USPN 8,116,992

Research is currently active on the patented technology "Method for Determining Solids Circulation Rate." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Embedded Gas and Temperature Sensors for Extreme Environments USPN 8,411,275; USPN 8,638,440; USPN 8,741,657; USPN 8,836,945; USPN 9,568,377; USPN 9,019,502; USPN 9,964,494

Research is active on optical sensors integrated with advanced sensing materials for high temperature embedded gas sensing applications. A portfolio of patented technologies are available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory (NETL). Organizations or individuals with capabilities in optical sensor packaging for harsh environment and high temperature applications are encouraged to contact NETL to explore potential collaborative opportunities.