CCS and Power Systems
Advanced Energy Systems - Coal and Coal/Biomass to Liquids
Investigation of Coal-Biomass Catalytic Gasification Using Experiments, Reaction Kinetics and Computational Fluid Dynamics
Performer: Virginia Polytechnic Institute and State University
Project No: FE0005476
Program Background and Project Benefits
The Department of Energy (DOE) is committed to supporting research focused on making use of the nation's coal and biomass resources. The Coal and Coal Biomass to Liquids (C&CBTL) Technology Program at DOE's National Energy Technology Laboratory (NETL) is developing advanced technologies to remove technical barriers that will foster the commercial adoption of coal and coal/biomass gasification technologies for the production of affordable hydrogen and liquid fuels (such as gasoline, diesel, aviation, and military fuels). The hydrogen can be used in advanced systems for efficient power generation produced with near-zero emissions and with the potential to significantly reduce greenhouse gas emissions. The synthesis gas (syngas) produced by the gasification of coal and coal/biomass mixtures can be converted by chemical processes to generate clean liquid hydrocarbon fuels. To successfully complete the development of C&CBTL technologies from the present state to the point of commercial readiness, the C&CBTL Program efforts are focused on two Key Technologies: (1) Coal/Biomass Feed and Gasification, and (2) Advanced Fuels Synthesis.
The Coal and Coal Biomass to Liquids Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal and/or coal-biomass mixtures. Activities support research for handling and processing of coal/biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on downstream components, catalyst and reactor optimization, and characterizing the range of products and product quality from the fuels conversion processes. Liquid fuels produced from coal/biomass feedstock not only reduce the nation’s dependency on foreign oil but also are cleaner burning than comparable petroleum products.
This Virginia Polytechnic Institute and State University project will use experimental reactor data to develop kinetic rate expressions for pyrolysis and char gasification for the coal-biomass blends under conditions free from transport limitations to develop a detailed understanding of the effect of pyrolysis conditions on the porous char structure. The impact of this project will be to develop a cost-effective gasification-based CBTL process to produce renewable liquid fuels that will provide diversity of fuel supply and energy security while resulting in lower future capital and operating costs. Specifically, this project will build mathematical models that combine true kinetic rate expressions with transport models for predicting gasification behavior for a broad range of pressures and temperatures, and investigate the physical and chemical parameters that might lead to synergistic effects in coal-biomass blends gasification.