Influence of Processing on Microstructure and Properties of Iron Aluminides and Coatings


INL - Idaho National Laboratory
Website:  Idaho National Laboratory
Award Number:  FWP-1168-100159
Project Duration:  10/01/2009 – 09/30/2014
Total Award Value:  $441,000.00
DOE Share:  $441,000.00
Performer Share:  $0.00
Technology Area:  Crosscutting Research
Key Technology:  Plant Optimization Technologies
The High-Velocity Oxy-Fuel thermal spray device at work.
The High-Velocity Oxy-Fuel thermal spray device at work.

Project Description

This project will determine the influence of thermal spray processing parameters on the microstructure, stress state, and performance of advanced coatings for high-temperature environmental resistance in fossil energy applications Advanced in situ diagnostics used in the application of coatings are employed to relate thermal spray particle characteristics to the observed coating microstructure and residual stress state. The state of total residual stress in the coating can be controlled by altering the thermal spray process parameters to control the relative importance of peening stress (which is known to be compressive) and the tensile quench stresses. A significant impact of the peening stress on the coating microstructure has also been observed.

A suite of coating performance tests will measure the effects of microstructure and stress state on important in-service coating characteristics, ultimately enabling selection of optimum coating parameters of a given alloy and application. The coating performance tests will encompass measurements of high-temperature oxidation and corrosion resistance at constant and cyclic well as providing measures of coating adhesion and durability both before and after environmental exposure. Demonstrated performance improvements of thermal spray coatings will lead to field testing. The repair of thermal spray coatings will also be explored.

Project Benefits

The search for cleaner processes and greater efficiencies in fossil energy power production has generated efforts to conduct fossil fuel based power production processes at higher operating temperatures and pressures. This has created a need for materials capable of withstanding elevated temperatures, pressures, and corrosive environments found in boilers and turbines.

Advanced coatings provide environmental degradation resistance to high-temperature structural alloys that may not otherwise have the corrosion resistance necessary for use in modern, high-efficiency, fossil-energy power plants. Thermal spray application of coatings is relatively inexpensive and rapid compared to conventional means, such as weld overlay application. High-temperature, corrosion-resistant coatings may enable the development of high-temperature, high-efficiency (greater than 50 percent conversion) power production, which can lead to a reduction of total greenhouse emissions, conservation of fossil energy reserves, and a decrease in U.S. dependency on foreign fossil energy sources.

The Idaho National Laboratory’s long history in the area of thermal spray coatings has focused on assessing the impact of various thermal spray parameters on coating characteristics (coating porosity, coating microstructure, residual stress in the coating, etc.), the development of coating compositions that resist environmental degradation, and thermal spray diagnostics. Feedback from advanced in situ diagnostics is used to control thermal spray parameters to produce consistent and reproducible coatings. It also allows the residual stress (compressive or tensile) in the coating/substrate system to be controlled and tailored to the desired application.

An effective test suite and optimized thermal spray methods and materials will contribute to the use of thermal and environmental barrier coatings in fossil energy power production. These coatings will permit the cost-effective operation of power plants at the elevated temperatures and pressures required to meet DOE’s efficiency and emissions targets. Achieving these targets will help to lower power production costs, conserve resources, limit dependence on foreign energy sources, and reduce emissions of greenhouse gases and other pollutants, thereby enhancing environmental management.

Goals and Objectives

The project’s goal is to increase the efficiency of power production from fossil fuels by enabling operation at higher temperatures and pressures. Specifically, the project will determine the influence of thermal spray processing parameters on the microstructure, stress state, and performance of advanced coatings for high temperature corrosion and oxidation resistance in fossil energy applications. Coating performance tests will include measures of coating adhesion, durability, and corrosion/oxidation resistance under constant and cyclic temperature conditions.

Contact Information

Federal Project Manager 
Vito Cedro:
Technology Manager 
Scott Smouse:
Principal Investigator 
Thomas Lillo:

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