Advanced Energy Systems - Hydrogen Turbines

High-Pressure Turbulent Flame Speeds and Chemical Kinetics of Syngas Blends with and without Impurities

Project No: FE0011778
Performer: Texas Engineering Experiment Station


Project Description

The project aims to further the understanding of how turbulent flame speeds vary for syngas blends under realistic engine conditions and compile and demonstrate the validity of a comprehensive kinetics model that can predict laminar flame speed and ignition behavior of high-hydrogen content fuels in the presence of likely contaminants and diluents. The project will utilize both flame speed and shock tubes test facilities to obtain fundamental combustion data relevant for chemical kinetics modeling. Experiments include existing flame speed and shock-tube facilities as well as a new high-pressure turbulent flame speed with a capability up to 20 atmospheres with a controllable and repeatable level of turbulence.

High-temperature, high-pressure laminar flame speed vessel.

High-temperature, high-pressure laminar flame speed vessel.


Program Background and Project Benefits

Turbines convert heat energy to mechanical energy by expanding a hot, compressed working fluid through a series of airfoils. Combustion turbines compress air, mix and combust it with a fuel (natural gas, coal-derived synthesis gas [syngas], or hydrogen), and then expand the combustion gases through the airfoils. Expansion turbines expand a working fluid like steam or supercritical carbon dioxide (CO2) that has been heated in a heat exchanger by an external heat source. These two types of turbines are used in conjunction to form a combined cycle— with heat from the combustion gases used as the heat source for the working fluid— improving efficiency and reducing emissions. If oxygen is used for combustion in place of air, then the combustion gases consist mostly of carbon dioxide (CO2) and water, and the CO2 can be easily separated and sent to storage or used for Enhanced Oil Recovery (EOR). Alternatively, the CO2/steam combustion gases can be expanded directly in an oxy-fuel turbine. Turbines are the backbone of power generation in the US, and the diverse power cycles containing turbines provide a variety of electricity generation options for fossil derived fuels. The efficiency of combustion turbines has steadily increased as advanced technologies have provided manufacturers with the ability to produce highly advanced turbines that operate at very high temperatures. The Advanced Turbines program is developing technologies in four key areas that will accelerate turbine performance, efficiency, and cost effectiveness beyond current state-of-the-art and provide tangible benefits to the public in the form of lower cost of electricity (COE), reduced emissions of criteria pollutants, and carbon capture options. The Key Technology areas for the Advanced Hydrogen Turbines Program are: (1) Hydrogen Turbines, (2) Supercritical CO2 Power Cycles, (3) Oxy-Fueled Turbines, and (4) Advanced Steam Turbines.

Hydrogen turbine technology research is being conducted with the goal of producing reliable, affordable, and environmentally friendly electric power in response to the Nation's increasing energy challenges. NETL is leading the research, development, and demonstration of technologies to achieve power production from high hydrogen content (HHC) fuels derived from coal that is clean, efficient, and cost-effective; minimize carbon dioxide (CO2) emissions; and help maintain the Nation's leadership in the export of gas turbine equipment. These goals are being met by developing the most advanced technology in the areas of materials, cooling, heat transfer, manufacturing, aerodynamics, and machine design. Success in these areas will allow machines to be designed that have higher efficiencies and power output with lower emissions and lower cost.

Texas A&M University will utilize both flame speed and shock tube test facilities to obtain fundamental combustion data relevant for chemical kinetics modeling. The project aims to further the understanding of how turbulent flame speeds vary for syngas blends under realistic engine conditions and compile and demonstrate the validity of a comprehensive kinetics model that can predict laminar flame speed and ignition behavior of high-hydrogen content fuels in the presence of likely contaminants and diluents. This research will improve the understanding of syngas combustion, leading to improved environmental performance of syngas combustors.



Contacts, Duration, and Cost

Contacts



Duration

Award Date: 10/01/2013
Project Date: 10/31/2016

Cost

DOE Share: $498,382.00
Performer Share: $124,595.00
Total Award Value: $622,977.00


Performer website: Texas Engineering Experiment Station - http://www.tamu.edu/