Water

COAL TO LIQUIDS AND WATER USE

Water Usage/Consumption for Coal to Liquids
Production of liquid transportation fuels from coal & biomass requires significant amounts of water, for three major purposes: 1) process cooling demands in coal conversion will often be met by wet evaporative cooling, which is associated with consumption of water through evaporation just as experienced in coal-based thermoelectric power plants, 2) water is consumed as the source of hydrogen necessary for transforming carbon-rich coal into liquid fuels having much higher hydrogen to carbon ratios than the coal, and 3) solids handling and dust control makes demands on water in mining operations, materials handling operations, ash disposal, etc. Table 1 shows the magnitude of water use by Sasol in South Africa for its mostly coal gasification-based liquid fuels production. Although these are aggregate numbers for all of Sasol’s production of a wide range of products, liquid fuels are the bulk of that production, so water use can be roughly correlated. For the most recent year, a total of about 25,000 tons of fossil fuel feedstocks were converted to about 24,000 tons of products, using about 147,000 tons of water. Therefore, the ratio of water use to product is approximately 6 to 1 by weight, or about 5 to 1 by volume assuming average product density is the typical diesel fuel density of 0.83kg/l.

Table 1. Sasol Water Use and Effluent Volumes Compared to Production and Major Feedstock Usage (source: Sasol Sustainable Development Report, 2013)

Year 2009 2010 2011 2012 2013
Total Production (kilotons) 22,039 24,548 25,228 25,302 23,696






Coal (kilotons) 16,994 17,315 17,019 17,040 17,896
Crude oil (kilotons) 4,493 4,331 4,890 5,492 3,392
Gas (kilotons) NR NR NR 4,031 3,616






Total water use (103 m3) 152,318 151,391 152,526 148,372 147,209
Liquid effluent (103 m3) 45,722 64,808 36,770 34,122 33,307
Water recycled  (103 m3) 130,562 139,308 128,719 142,754 145,466

NR Not Recorded

These approximate ratios are consistent with guidelines given in other estimates1, which have figured that water use at hypothetical CTL plants could vary from 1-1.5 barrel of water per barrel of product for a zero-discharge air-cooled plant, to 5-7 bbl water per barrel of product for a plant with water cooling and less use of waste heat for process heat or cogeneration (Sasol uses primarily water cooling).

The marked difference between water use in air-cooled CTL vs. water-cooled CTL underscores the fact that water use in liquid synthesis plants utilizing conventional water cooling is by far the most significant use of water in that process scenario. Intrinsic water consumption as the source of hydrogen (2nd type mentioned) and solids liquid and handling (3rd type mentioned) as enumerated above cannot be reduced in CTL, but water for cooling (1st type mentioned) can be reduced through different strategies for process cooling water management. Therefore, substantial reduction is possible in the area of highest water use, translating into significant impact overall.

Process Cooling Water Management
Much of the United States’ domestic coal, especially low-rank coals and low-sulfur sub-bituminous coal, is located in the arid West where water resources are already strained. This makes the prospect of large-scale coal to liquid fuels conversion all the more challenging from a water usage standpoint. This is underscored by recent NETL sponsored analysis examining production of zero sulfur diesel fuel from domestic coal2, specifically sub-bituminous coal which is generally found west of the Mississippi in the Powder River Basin (PRB). In certain cases examined in this analysis, CTL facilities using the PRB coal are assumed to be located in Montana where water resources would be scarce, requiring tight water management. Accordingly, three different strategies for process cooling water management were evaluated: (1) wet cooling using mechanical draft evaporative cooling towers; (2) hybrid cooling in which a closed loop, air-cooled condenser is utilized to condense steam exiting the low-pressure turbine – reducing evaporative cooling load and therefore water losses– and the remainder of the cooling needs are met through the use of mechanical draft evaporative cooling towers similar to those used in the first strategy; and (3) dry cooling in which air is blown through a dry-cooling tower to remove heat from a closed water loop, and the only water losses in the process cooling system are those associated with blow-down to maintain water quality. This provided quantitative insights into impacts water use reduction would have on the performance and economics of the facility.

All the cases in the study assumed Siemens entrained flow gasification with full water quench to produce raw synthesis gas from the coal feed. Conventional cold gas cleaning was assumed for sulfur removal and recovery and for bulk CO2 removal. Fuels synthesis using low temperature Fischer-Tropsch (FT) slurry phase reactor technology with iron based FT catalysts was also assumed. In "once-through" cases, clean syngas is passed through the FT reactors one time only with unconverted syngas and light hydrocarbons sent to gas turbines for power generation, creating a large quantity of power as a co-product. In "recycle" configurations, most of the unconverted syngas and light hydrocarbons are recycled back to the FT reactors (after CO2 removal) to increase liquids production; in these there is less co-produced power.

Table 2 provides the results of certain cases evaluated in the study, namely those that assumed utilization of sub-bituminous coal without added biomass.

Table 2. Configurations for Sub-bituminous Coal to Liquids Synthesis Plants

Cases Recycle FT Once-through FT
Cooling type Wet Dry Hybrid Wet Dry Hybrid
Efficiency, HHV (%) 53.0 51.3 52.2 50.6 50.1 50.5
Export Power (MW) 0.0 0.0 0.0 227.2 190.9 213.9
Parasitic Power (MW) 504.5 539.0 524.6 568.4 588.0 581.9
Water (gpm) 9,741 2,348 5,715 11,540 2,693 6,798
Water (bbl water/bbl FT product)   6.68   1.61   3.92   7.91   1.85   4.66
Coal ($MM/yr) 116 120 118 130 130 130
O&M ($MM/yr) 411 424 418 454 455 455
Total Overnight Cost ($MM) 7,020 7,400 7,255 7,836 8,015 7,975
Total Overnight Cost ($/DB) 140,380 148,020 145,100 156,720 160,300 159,480
Required Selling Price ($/bbl FT diesel) 112.7 118.1 115.9 117.3 120.7 119.4
Crude Oil Equivalent ( $/bbl petroleum) 93.9 98.4 96.6 97.8 100.6 99.5

First, the numbers for water usage in terms of barrels of water per barrel of product here again clearly show the significant difference in water use which ranges from relatively low for dry cooling to relatively high for wet cooling. However, examining other parameters such as process efficiency, costs and prices associated with produced liquids shows the penalties and higher prices that occur in reduced water use scenarios. Accordingly, the tradeoff between water savings and higher costs of products must be carefully considered in CTL process evaluations.

Direct CTL
In the discussion above the fuels synthesis is indirect, based on coal gasification followed by Fischer-Tropsch synthesis. Direct CTL is a significantly different process approach, but both indirect and direct coal liquefaction require water for the same reasons, i.e. from demands for process cooling, hydrogen demand, etc. However, in theory the higher intrinsic efficiency of direct CTL should correlate with somewhat lower water consumption.

This is evidenced in Table 3, which presents some characteristic numbers associated with Shenhua's CTL operations in China. It shows a water intensity of 7 ton/ton of product for direct coal liquefaction, considerably lower than the water intensity for indirect liquefaction at 11-12. Although the absolute value of the latter is higher than experienced at Sasol's indirect coal liquefaction in South Africa, Shenhua’s numbers serve to show that the relative magnitude of water use for direct coal liquefaction tends to be lower than that for indirect liquefaction. Recently, it appears that Shenhua’s direct liquefaction has a somewhat lower water intensity of about 6 ton/ton of product3 which is about equal to the water intensity Sasol reports for its indirect liquefaction operations.

Table 3. Shenhua Comparison of Coal Conversion Technologies4

Shenhua Comparison of Coal Conversion Technologies

Industrial Practice: Reduction of Water Use at Sasol
Sasol has pursued various initiatives in recent years at its coal conversion plants in South Africa, where water scarcity is of particular concern, with the aim of ensuring improved water use efficiency and ensuring greater security of supply. Substantial investment was made in a series of water-treatment processes to recover existing effluent, as part of major expansions at the Sasol Synfuels operation undertaken primarily to meet new fuel specifications. The result was no additional water demand notwithstanding the process expansions, along with a reduction of effluent discharged to the environment.

At Secunda, Sasol added a wastewater treatment plant, a bioremediation center, and a solidification plant to handle designated waste streams. Oil is recovered from wastewater (consisting of gasification effluent, reaction water, and oily sewer water from an API oil/water separator), which undergoes chemical as well as biological (fixed film and activated carbon) treatment, filtration, and chemical oxidation steps to achieve desired treated water quality. The treated water from this unit is sent to Secunda cooling water make-up (the bulk of these treated effluents is used in this way) or ash water make-up if it is not suitable for cooling water make-up. The main concern regarding the quality of treated water is a high level of salts originating from the chemical cleaning waste streams that are treated in the wastewater plant.

These improvements in wastewater management are consistent with a zero liquid effluent design approach.

References/Further Reading


1. Estimates assumed 2 barrels of product per ton of sub-bituminous coal of 9,000 Btu/lb value. “Coal to Liquids Water Usage.”

2. “Production of Zero Sulfur Diesel Fuel from Domestic Coal: Configurational Options to Reduce Environmental Impact,” December 2011 DOE/NETL-2012/1542.

3. 6.65 million tons water used per 1.08 million tons of liquid products in 2013, i.e. 6.2 ton/ton or 5.1 bbl/bbl water intensity (diesel fuel basis); refer to “Thirsty Coal 2: Shenhua’s Water Grab,” Greenpeace, 2013-07-23.

4. Shenhua Coal Conversion Technology and Industry Development, Yuzhuo Zhang, Shenhua Group Corporation Ltd., China.


Water

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